离子交换树脂催化合成丙烯酸正丁酯   总被引：2，自引：0，他引：2  

许文苑  熊国宣  彭道峰 《华东地质学院学报》2000,23(4):328-331,338

论述了以丙烯酸、正丁醇为原料,离子交换树脂作催化剂,催化合成丙烯酸正丁酯的新工艺。考察了催化剂种类、用量、原料配比、反应时间、阻聚剂用量以及催化剂使用次数等因素对酯化率的影响,确定了催化剂种类和最佳工艺条件。结果表明,７３１强酸性离子交换树脂具有良好的催化活性和选择性,可多次重复使用,酯化率可达８２．０％,产品质量符合国家标准,该工艺操作简单,条件容易控制,对环境无污染。  相似文献   

Export of Acidity in Drainage Water from Acid Sulphate Soils     

F.J Cook  W Hicks  E.A Gardner  G.D Carlin  D.W Froggatt 《Marine pollution bulletin》2000,41(7-12):319-326

Disturbed acid sulphate soils are potent sources of acidity in coastal waterways. Monitoring studies of the drainage water for sites at East Trinity, Cairns and Pimpama, south-east Queensland indicate that considerable acidity is found in the drainage water from these sites. Hydrogen (H⁺), ferrous (Fe²⁺) and aluminium (Al) ions are the dominant acid cations involved. When drainage water is mixed with fresh or marine waters the effect of H⁺ on acidity generation is immediate. Aluminium can release acidity on hydrolysis, while the oxidation of Fe²⁺ to Fe³⁺ both acidifies and removes dissolved oxygen from the water. Strongly acidic waters with low levels of dissolved oxygen concentration are undesirable for most forms of aquatic life. Export of acidity from acid sulphate soil is likely to have a major effect on inshore fisheries and breeding grounds especially in periods of flood following drought or periods of low rainfall, where large volumes of acidity can be flushed/leached into sensitive aquatic/marine habitats. Impacts may include low dissolved oxygen, fish kills, epizootic ulceration syndrome and damage to oysters. During the processes of oxidation and hydrolysis, iron and aluminium flocs form, that can smother benthic communities. Heavy metals are found in the drainage water at elevated levels and may also be of concern for aquatic organisms. Chronic effects such as habitat degradation, mortality of marine worms, bivalves, invasion of acid tolerant species (both plant and animal) and avoidance of habitat have been documented elsewhere. These areas require further research.  相似文献   

OB association members in the ACT and TRC catalogues     

Ronnie Hoogerwerf 《Monthly notices of the Royal Astronomical Society》2000,313(1):43-65

The Hipparcos Catalogue contains members of nearby OB associations brighter than 12th magnitude in V . However, membership lists are complete only to magnitude V =7.3. In this paper we discuss whether proper motions listed in the 'Astrographic Catalogue+Tycho' reference catalogue (ACT) and the Tycho Reference Catalogue (TRC), which are complete to V ∼10.5 mag, can be used to find additional association members. Proper motions in the ACT/TRC have an average accuracy of ∼3 mas yr⁻¹. We search for ACT/TRC stars which have proper motions consistent with the spatial velocity of the Hipparcos members of the nearby OB associations already identified by de Zeeuw et al. These stars are first selected using a convergent-point method, and then subjected to further constraints on the proper-motion distribution, magnitude and colour to narrow down the final number of candidate members. Monte Carlo simulations show that the proper-motion distribution, magnitude, and colour constraints remove ∼97 per cent of the field stars, while at the same time retain more than 90 per cent of the cluster stars.
The procedure has been applied to five nearby associations: the three subgroups of Sco OB2, plus Per OB3 and Cep OB6. In all cases except Cep OB6, we find evidence for new association members fainter than the completeness limit of the Hipparcos Catalogue. However, narrow-band photometry and/or radial velocities are needed to pinpoint the cluster members, and to study their physical characteristics.  相似文献   

Low-mass spectroscopic binaries in the Hyades: a candidate brown dwarf companion     

I. Neill Reid  S. Mahoney 《Monthly notices of the Royal Astronomical Society》2000,316(4):827-844

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STUDY ON THE ISOTHERMS OF THE INTERACTION BETWEEN SUSPENDED PARTICLES AND Cu (Ⅱ) IN THE HUANGHE RIVER   总被引：1，自引：0，他引：1  

李改枝  郭博书  刘颖  红霞  李景峰  李北罡 《中国海洋湖沼学报》2000,18(2)

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｖａｒｉｏｕｓｐｈｙｓｉｃａｌａｎｄｃｈｅｍｉｃａｌｒｅａｃｔｉｏｎｓｔｈａｔｏｃｃｕｒｂｅｔｗｅｅｎｔｈｅｓｕｓｐｅｎｄｅｄｐａｒｔｉｃｌｅｓ,ｓｅｄｉｍｅｎｔｓ,ｅｔｃ.ａｎｄｈｅａｖｙｍｅｔａｌｓｉｎａｎａｔｕｒａｌａｑｕａｔｉｃｓｙｓｔｅｍｐｌａｙｅｘｔｒｅｍｅｌｙｉｍｐｏｒｔａｎｔｐａｒｔｓｉｎｃｏｎｔｒｏｌｌｉｎｇｔｈｅｄｉｓｔｒｉｂｕｔｉｏｎｐａｔｔｅｒｎ,ｍｉｇｒａｔｉｏｎａｎｄｔｒａｎｓｆｏｒｍａｔｉｏｎｏｆｈｅａｖｙｍｅｔａｌｓｔｈｅｒｅ.Ｓｉｎｃｅ…  相似文献   

A moving group of young stars in Carina–Vela     

Valeri V. Makarov  Sean Urban 《Monthly notices of the Royal Astronomical Society》2000,317(2):289-298

Accurate two-colour photometry and proper motions of 7096 young X-ray stars in the ROSAT All-Sky Survey Bright Star Catalogue, version 1RXS, are extracted from the Tycho-2 Catalogue. The sample is dominated by red main-sequence and possibly pre-main-sequence stars. On a global proper motion convergence map, two features are very prominent: the nearby section of the Gould Belt and the Hyades convergent point. The appearance of the Gould Belt feature with its peak at ( l =2443, b =−126) is quite similar to that of Hipparcos OB stars. When only stars with proper motions drawing close to that point are selected, strong concentrations of stars in the direction of the Sco–Cen complex are found. Another concentration, not corresponding to any known OB association, is detected between the position of the Lower Centaurus Crux and Vela OB2 associations. It is a new young moving group located in Carina and Vela, and a near extension of the Sco–Cen complex. Contrary to the classical Gould Belt OB associations, the Carina–Vela moving group has a considerable geometric depth, the closest members being as near as 30 pc from the Sun. IC 2391, one of the youngest and closest open clusters on the sky, is a part of the Carina–Vela moving group. The Carina–Vela moving group does not link the Sco–Cen complex with the Vela OB associations, because the latter is much more distant than the outer limit of the sample. It is more likely that the young late-type population of the Scorpio–Centaurus–Carina moving group stretches towards the Sun and possibly beyond it.  相似文献   

D290树脂从石煤酸浸液中吸附钒的工艺   总被引：13，自引：0，他引：13  

张云  范必威  林海玲  马江舟  陆世银  王海平  吕树环 《矿物岩石》2000,20(4):95-98

本文主要研究Ｄ２９０树脂从石煤酸浸液中回收钡的工程过程,并在树脂选型、树脂上柱条件,洗脱液的组成等方面进行了详细实验,采用酸浸－离子交换新工艺后,可在减化流程,降低消耗的同时使回收率提高１５％以上。  相似文献   

An FTIR product study of the photooxidation of dimethyl disulfide     

I. Barnes  K. H. Becker  N. Mihalopoulos 《Journal of Atmospheric Chemistry》1994,18(3):267-289

The products of the 254 nm photolysis of ppm levels of DMDS have been studied as a function of the O₂ partial pressure at 760 Torr (N₂ + O₂) and 298±2 K. The major sulfur containing compounds detected were SO₂ and CH₃SO₃H (methane sulfonic acid, MSA) and the major carbon containing compounds were CO, HCHO, CH₃OH and CH₃OOH (methyl hydroperoxide). Within the experimental error limits the observed sulfur and carbon balances were approximately 100%. CH₃OOH has been observed for the first time in such a photooxidation system. Its observation provides evidence for the formation of CH₃ radicals by the further oxidation of the CH₃S radicals formed in the primary photolysis step.From the behavior of the DMDS photolysis products as a function of the O₂ partial pressure, O₃ concentration and added OH radical source it is postulated that the further reactions of CH₃SOH (methyl sulfenic acid), formed in the reaction OH + CH₃SCCH₃ CH₃SOH + CH₃S, are the main source of MSA in the 254 nm photolysis of DMDS.Some of the possible implications of the results of this study for the degradation mechanisms of other atmospherically important organic sulfur compounds, in particular DMS, are briefly considered.  相似文献   

平朔露天矿太原组11^#和9^#煤层的沉积环境分析     

程东  柴东浩 《高校地质学报》1998,4(4):465-472

平塑露天矿的露采煤层,即１１＾＃和９＾＃煤层是上石炭统太原组Ⅱ－Ⅲ层段扇三角洲－泻湖及扇三角洲－潮坪环境的产物。厚４ｍ的１１＾＃煤层形成于扇三角洲－潮坪环境中,厚１５ｍ的９＾＃煤层形成了扇三角洲平原,扇三角洲前缘（北西部）以及覆水较深的泻湖（中南部）环境中。  相似文献   

On the formation of massive stars     

Ian A. Bonnell  Matthew R. Bate  & Hans Zinnecker 《Monthly notices of the Royal Astronomical Society》1998,298(1):93-102

We present a model for the formation of massive ( M ≳10 M⊙) stars through accretion-induced collisions in the cores of embedded dense stellar clusters. This model circumvents the problem of accreting on to a star whose luminosity is sufficient to reverse the infall of gas. Instead, the central core of the cluster accretes from the surrounding gas, thereby decreasing its radius until collisions between individual components become sufficient. These components are, in general, intermediate-mass stars that have formed through accretion on to low-mass protostars. Once a sufficiently massive star has formed to expel the remaining gas, the cluster expands in accordance with this loss of mass, halting further collisions. This process implies a critical stellar density for the formation of massive stars, and a high rate of binaries formed by tidal capture.  相似文献